Beat the following modes/chapters to unlock these characters:
| One Stage Of Free Mode | Marshall Law |
| Challenge Mode | Paul Phoenix |
| Chapter 1 in free mode with B or above in all missions. | Kelly |
| Chapter 1 in free mode with B or above in all missions. | Vera Ross |
| Chapter 1 in free mode with B or above in all missions. | Lilian |
| Chapter 2 in free mode with B or above in all missions. | McKinzie |
| Chapter 2 in free mode with B or above in all missions. | Napalm99 |
| Chapter 3 in free mode with B or above in all missions. | Ling Fong |
| Chapter 3 in free mode with B or above in all missions. | Golem |
| All chapters in free mode with A rank in all missions | Shinkai |
| All chapters in free mode with S rank in all missions | Bordin |