Unlockable Difficulties
| Chaos Difficulty | Clear Musou Mode with 1 character from Wu, Shu, Wei, and Other |
| Very Hard Difficulty | Clear Musou Mode with any 1 character |
Unlockable characters
| Cao Cao | Clear Musou Mode with 3 Wei characters |
| Cao Pi | Deafeat Cao Pi within 5 minutes on Wu side of He Fei |
| Diao Chan | Clear Musou Mode with 1 character from each Kingdom |
| Dong Zhuo | Clear Musou Mode with Lu Bu |
| Gan Ning | Clear Musou Mode with 1 Wu character |
| Guan Ping | Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive |
| Huang Zhong | Succeed in 1 battle objective on the Wei side of Ding Jun Mountain |
| Liu Bei | Clear Musou Mode with 3 Shu characters |
| Lu Bu | Clear Musou Mode with Liu Bei, Cao Cao, and Sun Jian |
| Lu Meng | Succeed in 2 battle objectives on the Wei side of He Fei |
| Ma Chao | Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle |
| Pang Tong | Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Sun Jian | Clear Musou Mode with 3 Wu characters |
| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Xiahou Yuan | Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xu Huang | Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
| Zhang Liao | Clear Musou Mode with 1 Wei character |
| Zheng He | Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle |
| Zhang Jiao | Zhang Jiao:Defeat him in the Yellow Turban Rebellion stage |
| Zhou Tai | Succeed in 3 battle objectives on the Shu side of Yi Ling |
| Zhuge Liang | Clear Musou Mode with 1 Shu character |